MF-ZS Sulfur-Impregnated Coconut Shell Carbon | Mercury Oxidation & Capture

Sulfur-impregnated coconut shell activated carbon for enhanced elemental mercury capture. Chemically bound sulfur oxidizes and stabilizes Hg⁰ as HgS in low-chlorine flue gas, cement kiln, and industrial process applications.

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Product Overview

Elemental mercury (Hg⁰) presents a unique capture challenge: it is insoluble, volatile, and barely interacts with untreated carbon surfaces. MF-ZS solves this by starting with a high-activity coconut shell base and integrating sulfur through controlled impregnation, creating dedicated chemisorption sites across the pore network.

Rather than relying on physical mixing, the sulfur is chemically anchored to the coconut shell carbon matrix. This ensures the active phase remains fixed during pneumatic conveying, storage, and injection—no segregation, no dusting hazards, and no premature depletion. Once deployed in flue gas or process streams, these sulfur sites oxidize elemental mercury and bind it as stable mercuric sulfide (HgS), a compound that stays locked within the carbon structure through handling, transport, and final disposal.

Specifications

Technical SpecificationsMF-ZSUnit
Iodine adsorption value> 1000mg/g
Moisture content< 10%-wt
Ash content< 5%-wt
Hardness> 95-
Fe< 0.1%
Mg< 0.05%

Key Application Areas

  • Coal-fired power generation — enhanced Hg⁰ capture in low-chlorine flue gas where standard activated carbon injection underperforms
  • Cement manufacturing — control of mercury re-emission from kiln dust recycle loops and preheater exhaust
  • Precious metals roasting — capture of mercury volatilized during gold ore thermal processing
  • Chlor-alkali remediation — containment and removal of residual mercury from decommissioned cell rooms and contaminated buildings
  • Natural gas treatment — removal of trace mercury from hydrocarbon gas streams to protect downstream catalysts and pipelines

Advantages Over Standard ACI Carbons

MF-ZS is purpose-built for conditions where Hg⁰ is the primary species:

  • Coconut Shell Base Structure: Hard, low-ash coconut shell carbon withstands pneumatic attrition and maintains particle integrity during injection and transport
  • Chemically Bound Sulfur Phase: Sulfur is grafted to the surface, not dry-blended, eliminating handling risks and ensuring uniform activity throughout the bed or injection plume
  • Superior Low-Chlorine Performance: Delivers 30–50% higher elemental mercury capture than standard unimpregnated ACI carbons in flue gas with limited natural halogen content
  • Stable Waste Form: Captured mercury converts to insoluble HgS, dramatically reducing leaching potential in landfill disposal compared to physically adsorbed mercury
  • Lower Carbon Usage Rates: Higher intrinsic capture efficiency per unit mass translates to reduced injection quantities, lower fly ash burden, and decreased material costs over the operating cycle
  • Full-Scale Validation: Proven in utility-scale trials under real flue gas conditions, not just laboratory spiked-gas tests

  • Q
    How does sulfur impregnation improve elemental mercury capture?
    A

    Elemental mercury (Hg⁰) is insoluble, volatile, and barely interacts with untreated carbon surfaces. MF-ZS integrates sulfur through controlled impregnation, creating dedicated chemisorption sites. The sulfur is chemically anchored to the coconut shell carbon matrix, oxidizing elemental mercury and binding it as stable mercuric sulfide (HgS) that remains locked within the carbon structure.

  • Q
    What advantages does MF-ZS offer over standard ACI carbons?
    A

    MF-ZS delivers 30–50% higher elemental mercury capture than standard unimpregnated carbons in low-chlorine flue gas. The chemically bound sulfur eliminates handling risks and ensures uniform activity. Captured mercury converts to insoluble HgS, dramatically reducing leaching potential in landfill disposal compared to physically adsorbed mercury.

  • Q
    In what specific conditions is MF-ZS preferred over MF-Z?
    A

    MF-ZS is purpose-built where Hg⁰ is the primary species, particularly in low-chlorine flue gas where standard activated carbon injection underperforms. Applications include coal-fired power generation with low natural halogen content, cement manufacturing controlling mercury re-emission from kiln dust recycle loops, and precious metals roasting where mercury volatilizes during gold ore thermal processing.

  • Q
    Does sulfur loading affect the base carbon's physical properties?
    A

    Sulfur content of 8–15% slightly reduces iodine number from the base carbon value, but the trade-off is justified by the specific mercury capture enhancement. Bulk density increases to 450–550 kg/m³ due to sulfur mass, while the hard coconut shell base maintains structural integrity during pneumatic conveying and injection. Custom sulfur loadings are available for specific applications.

Packaging & Shipping

Packaging:

To meet diverse customer requirements, our activated carbon is available in multiple packaging options:

  • 20 kg/bag – Ideal for laboratory use, pilot testing, and small-scale applications.
  • 500 kg/bag – Bulk packaging designed for large-scale industrial production.
  • Customized packaging available upon request.

All packages are engineered to maintain quality and prevent moisture absorption.

Shipping:

  • Fast delivery within 15-30 days
  • Export standard packaging
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